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I688F

Category 4 — Stable Fold, Function DisruptedLikely pathogenicLumenal · predictedσ-1 candidateEditorial
IsoleucinePhenylalanine at position 688 · C-terminal lumenal domain (653-869) · WFS1 (Wolframin)

Isoleucine → Phenylalanine at position 688 in wolframin's C-terminal lumenal domain. ClinVar Likely pathogenic for Wolfram syndrome 1. AlphaMissense 0.406 (below threshold) — AM under-call. DynaMut2 ΔΔG -0.64 kcal/mol (destabilising).

Interactive 3D Structure

Wild-type reference
Wild-type I688 — hydrogen bond to S691
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DynaMut2 mutant · I688F
Mutant F688 — hydrogen bond contact to R685 lost
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Bond changes · DynaMut2 interaction analysis

1 lost0 gained7 preserved
Interaction typeWild-type partnerMutant partnerStatus
Hydrogen bondA684A684Preserved
Hydrogen bondR685Lost
Hydrogen bondS691S691Preserved
Polar contactA684A684Preserved
Polar contactR685R685Preserved
Polar contactT686T686Preserved
Polar contactS691S691Preserved
Van der WaalsA684A684Preserved

Lost / gained / preserved interatomic contacts at the variant residue, from the DynaMut2 (Arpeggio) interaction analysis of the wild-type and energy-minimized mutant structures.

Computational Predictions

DynaMut2 ΔΔG
-0.64kcal/mol
Destabilising — mild
AlphaMissense
0.406
Amb
AlphaFold pLDDT
89
model confidence
Schema
Cat 4
Category 4 — Stable Fold, Function Disrupted
ΔΔG confidence: Standard confidence · Lumenal

This variant is in a water-facing region, which is the regime the stability predictor was built and benchmarked for. Ordinary predictor error still applies.

Clinical Evidence

ClinVar classificationLikely pathogenic
Review statuscriteria provided, single submitter
Associated conditionsWolfram syndrome 1
InheritanceWolfram syndrome 1 (AR) documented.
Population frequency (gnomAD v4)Absent from gnomAD v4
cDNA changec.2062A>T
ClinVar accessionVCV003393279
Last evaluated2024/12/19 00:00

Not observed in ~730k individuals — consistent with a rare allele (ACMG PM2_supporting).

Classified for1★ unverified submission

ClinVar classifies this variant as Likely pathogenic for Wolfram syndrome (classic) (autosomal recessive, OMIM 222300). Classic Wolfram syndrome is recessive: a single copy does not produce it, and this classification says nothing about a carrier's own risk.

  • Wolfram syndrome (classic)autosomal recessive · OMIM 222300submitted as: Wolfram syndrome 1
  • This rests on a single submitter (1★). Treat the conditions above as submitted, not as documented phenotypes.
  • Phenotype scope is interpretation of submitted records. The computed values on this card (AlphaMissense, DynaMut2 ΔΔG, pLDDT) are measurements of the model, not of a patient.
  • Presentation cannot be generalised from neighbouring variants: one nucleotide over can present very differently. Structural similarity supports a mechanistic hypothesis, never a phenotype claim.

Review status: 1★ single submitter. ClinVar "conditions" is the union of all submissions; 0–1★ entries are submitted conditions, not documented phenotypes.

Population frequency
Global (all ancestries)
Absent from gnomAD v4
Homozygotes
Not available

No population breakdown — the variant is absent from gnomAD v4, so no ancestry group has an observed frequency.

No homozygotes — the variant is absent from gnomAD v4 altogether.

Source: gnomAD r4, retrieved 2026-08-21. Values are allele frequencies. The carrier estimate is derived from the allele frequency (Hardy-Weinberg, ~2·AF) and is an approximation, not a published figure — where a published carrier frequency exists it outranks this column and is cited on the card.

Structural Context

Position 688 sits adjacent to several R558 microregion-related residues. The AlphaFold model places I688 within 5 Å of LEU689 (2.5 Å), GLN687 (2.5 Å — partner of Q687H Atlas card), ARG685 (3.8 Å — partner of R685P), SER691 (3.9 Å), and ALA684 (4.0 Å — partner of A684T and A684V).

Replacing I688 with phenylalanine adds aromatic volume to a tightly-packed region containing R685, A684, Q687 — all known pathogenic variant positions. The F688 introduction reorganizes the local packing.

The |ΔΔG| of 0.64 reflects fold accommodation. AlphaMissense's 0.406 is below threshold — AM under-call. ClinVar Pathogenic + Wolfram 1 establishes clinical relevance.

Amino-acid chemistry
Isoleucine (I) → Phenylalanine (F) — branched aliphatic hydrophobic replaced by aromatic hydrophobic.
Position in the protein
C-terminal lumenal domain · position 688 in the ER lumen (pLDDT 89).

Druggability Assessment

Category 3/4 — Most Druggable (AM under-call). |ΔΔG| = 0.64 — fold survives. AlphaMissense 0.406 below threshold but ClinVar Pathogenic + Wolfram 1.

Mechanism is volume mismatch in the R685-A684-Q687 multi-variant microregion. Therapeutic strategy: same target cluster as A684T, A684V, R685P, Q687H.

Why this matters

I688F joins the dense 684-688 multi-variant cluster — six Atlas variants (A684T, A684V, R685P, Q687H, I688F, plus broader region) converge here.
Therapeutic Strategy Handoff · prediction

Feed this card to Wolfram Intelligence

Download the I688F PDF below and upload it to Wolfram Intelligence to generate therapeutic-strategy proposals — guanidinium mimetics, sigma-1 agonist docking, NAC thiol-capping. NAC is already on the bench-testing list.

Download I688F PDF card ↓Strategies are AI-generated predictions, not validated therapeutics.

UniProt Domain Annotation

Chain1890 · Wolframin
Topological domain653869 · Lumenal